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Metal-mercaptide chemistry. The synthesis and structural characterization of the [Cu(SC6H5)3]2- anion. A rational synthesis and the structure of the [Cu4(SC6H5)6]2- cluster

✍ Scribed by Coucouvanis, D.; Murphy, C. N.; Kanodia, S. K.


Book ID
126979169
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
845 KB
Volume
19
Category
Article
ISSN
0020-1669

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## Abstract The reaction of PhSeSiMe~3~, CuCl, InCl~3~, and Ph~4~AsCl in CH~2~Cl~2~ results in crystals of the structurally closely related, ionic clusters (AsPh~4~)~2~[Cu~6~In~4~Cl~4~(SePh)~16~] and (AsPh~4~)[Cu~7~In~4~(SePh)~20~], with product ratios dependent on the initial PhSeSiMe~3~ concentra