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Metal-Mediated Transfer of Electrons between Two Different C−C Single Bonds That Function as Electron-Donor and Electron-Acceptor Units

✍ Scribed by Federico Franceschi; Euro Solari; Rosario Scopelliti; Carlo Floriani


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
125 KB
Volume
39
Category
Article
ISSN
0044-8249

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Metal-Mediated Transfer of Electrons bet
✍ Federico Franceschi; Euro Solari; Rosario Scopelliti; Carlo Floriani 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB 👁 1 views

Scheme 1. Reversible two-electron oxidative (a) and reductive coupling (b) to form CÀC bonds. R Et. from triplet states of a ligand-to-metal charge transfer character that mix with metal-centered (ds/dp) states modified by Au ´´´Au interactions (LMMCT; S 3Au), whereas the high-energy emission at ca