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Metal localized luminescence in rhodium (III) and iridium (III) sulphur chelates

✍ Scribed by J.E. Hillis; M.K. DeArmond

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
358 KB
Volume
10
Category
Article
ISSN
0009-2614

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✦ Synopsis

Emission and absorption sTect.ra (liquid nitrogen temperature) are reported for the tris sulphur chelates of dkthyldithiophosphate (dtp) and diiethyldithiocarbamate (dmtc) with rhodium(II1) and tidium(III) ions. The emission for a.If complexes is broad, structureless and occurs in the ne;LE Infrared. Emission Iifetimes are slt FJICW magnitude. The emission is assigned as a metal locaked 3T1 -t 'Al 'emission.

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