Metal-Ligand Stability Constants of Complexes of substituted ortho-hydroxyacetophenones with iron, cobalt and nickel
✍ Scribed by Dr. P. V. Kamat; Dr. M. G. Datar
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 342 KB
- Volume
- 315
- Category
- Article
- ISSN
- 1615-4150
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Metal‐ligand stability constants of complexes of substituted ortho‐hydroxyacetophenones and ortho‐hydroxypropiophenones with iron, cobalt and nickel were studied potentiometrically, at 27°C, at an ionic strength of μ∼0.1 M NaClO~4~, by CALVIN‐BJERRUM titration method. The stepwise stability constants thus determined are correlated with the nature of the substituents in the benzene nucleus of the ligands employed.
📜 SIMILAR VOLUMES
## Abstract Divalent nickel, cobalt and iron complexes {[(bmppa)Ni(CH~3~CN)](ClO~4~)~2~ (1), [(bmppa)Co(CH~3~CN)](ClO~4~)~2~ (2), [(bmppa)Fe(CH~3~CN)](ClO~4~)~2~ (3)} of an amide‐appended N~2~S~2~‐donor ligand {bmppa = __N__,__N__‐bis(2‐methylthio)ethyl‐__N__‐[(6‐pivaloylamido‐2‐pyridyl)methyl]amin
## Abstract The syntheses and characterization of four new linear pentadentate ligands and their Co^III^ complexes are described: __N__,__N__′‐[(pyridine‐2,6‐diy)bis(methylene)]bis[sarcosine] (sarmp), __N__,__N__′‐[(pyridine‐2,6‐diyl)bis(methylene)]bis[(__R__)‐ or (__S__)‐proline] ((__R__,__R__)‐ o