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Metal-Ligand Stability Constants of Complexes of substituted ortho-hydroxyacetophenones with iron, cobalt and nickel

✍ Scribed by Dr. P. V. Kamat; Dr. M. G. Datar


Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
342 KB
Volume
315
Category
Article
ISSN
1615-4150

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✦ Synopsis


Abstract

Metal‐ligand stability constants of complexes of substituted ortho‐hydroxyacetophenones and ortho‐hydroxypropiophenones with iron, cobalt and nickel were studied potentiometrically, at 27°C, at an ionic strength of μ∼0.1 M NaClO~4~, by CALVIN‐BJERRUM titration method. The stepwise stability constants thus determined are correlated with the nature of the substituents in the benzene nucleus of the ligands employed.


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