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METAL-LIGAND ELECTRON TRANSFERS IN VANADIUM COMPLEXES OF 11-TUNGSTOSILICATE ISOMERS

✍ Scribed by Hervé, G.; Tézé, A.; Leyrie, M.

Book ID
121491046
Publisher
Taylor and Francis Group
Year
1979
Tongue
English
Weight
277 KB
Volume
9
Category
Article
ISSN
0095-8972

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## Abstract New fascinating electronic features of the simple diketoamine chelate ligand HN[CH~2~C(__t__Bu)O]~2~ (1) are described. Unexpectedly, the corresponding trianionic amido‐dienolate form of 1 is capable of reducing main‐group metal atoms M after initial coordination and intramolecular L→M