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Metal Ions as Allosteric Inhibitors in Hydrogen-Bonding Receptors

โœ Scribed by Mohammad H. Al-Sayah; Neil R. Branda

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
92 KB
Volume
112
Category
Article
ISSN
0044-8249

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## Abstract Isocytosine (ICH; 1) exists in solution in an equilibrium of tautomers 1โ€‰a and 1โ€‰b with the __N__^1^ and __N__^3^ positions carrying the acidic proton, respectively. In the solid state, both tautomers coexist in a 1:1 ratio. As we show, the __N__^3^H tautomer 1โ€‰b can selectively be crys