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Metal-ion oxidations in solution. Part XII. Oxidation of thiourea and NN?-ethylenethiourea by chromium(VI) in perchlorate media

โœ Scribed by Olatunji, M. Adegboyega; McAuley, Alexander


Book ID
120183459
Publisher
The Royal Society of Chemistry
Year
1975
Tongue
English
Weight
794 KB
Volume
8
Category
Article
ISSN
1472-7773

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Kinetics and mechanism of oxidation of d
โœ Kalyan Kali Sen Gupta; Shipra Sen Gupta; Subrata Kumar Mandal; Samarendra Nath B ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 359 KB

The kinetics of oxidation of D-glucopyranose 6-phosphate and D-ribofuranose 5-phosphate by chromium(V1) in perchloric acid media have been studied by U.V. spectroscopy. Each reaction is first order with respect to [chromium(VI)] and [substrate]. The reactions are acid-catalysed and accelerated by th