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Metal Ion Induced Rearrangements of Bisbenzthiazolines to Schiff-Base Chelates

✍ Scribed by Jadamus, Hans.; Fernando, Quintus.; Freiser, Henry.


Book ID
120176663
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
477 KB
Volume
86
Category
Article
ISSN
0002-7863

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Metal ion - base catalyzed rearrangement
✍ Stan S. Hall; Albert Poet πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 French βš– 107 KB

We have observed that a-ketohemimercaptals, formed (2) by equilibrating a-ketoaldehyde mrmohydrates with thiols (3), rearrcmge exceedingly slowly in the presence of one equivalent of sodium ocetote (180 h) and somewhat faster in the presence of an equivalent of a tertiary amine (4) such as N-methylp