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Metal ion effects in intramolecular reactions. Effects of divalent metal ions on intramolecular acetamido group participation in ester hydrolysis

โœ Scribed by Fife, Thomas H.; Przystas, Theodore J.; Pujari, Mahesh P.


Book ID
125511777
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
904 KB
Volume
110
Category
Article
ISSN
0002-7863

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โœ Thomas H. Fife; M.P. Pujari ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 207 KB

Rate constants have been determined for hydrolysis of the acetate, glutarate, and phthalate monoesters of 2-hydroxy-1,10-phenanthroline in water at 30 degrees C and &mgr = 0.1 M with KCl. The hydrolysis reactions of the esters are hydroxide ion catalyzed at pH > 9. The phthalate and glutarate monoes