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Metal Ion Decomposition of Hydroperoxides. III. Intermediates in Cobalt Salt Catalyzed Decomposition of t-Butyl Hydroperoxide 1a

✍ Scribed by Richardson, William H.


Book ID
126423388
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
630 KB
Volume
30
Category
Article
ISSN
0022-3263

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On the cobalt-catalyzed decomposition of
✍ J. A. Bigot 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 316 KB

## Abstract The cobalt‐catalyzed decomposition of __tert.__‐butyl hydroperoxide in the presence of a number of five‐membered heterocycles is described. With tetrahydrofuran displacement of the alpha‐hydrogen atom by a peroxy group is observed; with furan and pyrrole 1.4 addition of peroxy radicals