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Metal Ion Catalyzed Autoxidation Reactions: Kinetics and Mechanisms

✍ Scribed by Istvan Fabian; Viktor Csordas


Publisher
John Wiley and Sons
Year
2003
Weight
51 KB
Volume
34
Category
Article
ISSN
0931-7597

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The kinetics and mechanism of electron transfer between stable verdazyl radicals via bridge Mn(II), Co(II), Ni(II), Cu(I), and Zn ions have been studied in the range 280-330 K using the stopped-flow technique. It was found that the kinetic features of the reactions could be described in terms of the