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Metal Ion Catalysis in the Hydrolysis of Schiff Bases 1,2

โœ Scribed by Eichhorn, Gunther L.; Bailar, John C.

Book ID
125940573
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
343 KB
Volume
75
Category
Article
ISSN
0002-7863

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The rates of hydrolysis of N-(2&4-hydroxybenzylidene)-2-aminobenzothiazoles has been studied in the pH range 4-13 in a 10% dioxane-water system and in various nonionic surfactant systems. The reaction is found to be due to water mediated intramolecular general base catalysis within the pH range 4.0