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Metal-halogen exchange reactions of 1,5-diiodonaphthalene. Synthesis of 1,5-disubstituted naphthalene derivatives

โœ Scribed by Wang, Wuyi; D'Andrea, Stan V.; Freeman, Jeremiah P.; Szmuszkovicz, Jacob


Book ID
127079130
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
292 KB
Volume
56
Category
Article
ISSN
0022-3263

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Lithiated Azafulvenes by Halogen/Metal I
โœ Brian L. Bray; Petr Hess; Joseph M. Muchowski; Markus E. Scheller ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 244 KB

The first known lithiated 1-azafulvene derivatives were generated by low-temperature halogen/metal interchange, with r-BuLi, from the corresponding brominated 6-diisopropylamino compounds 3b and 12. These Li species reacted with sundry electrophilic reagents to give products which, on basic hydrolys