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Metal-Free Oxidative C(sp 3 )–H Bond Thiolation of Ethers with Disulfides

✍ Scribed by Guo, Sheng-rong; Yuan, Yan-qin; Xiang, Jian-nan

Book ID
120978789
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
709 KB
Volume
15
Category
Article
ISSN
1523-7060

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✍ Zhao, Jincan; Fang, Hong; Han, Jianlin; Pan, Yi; Li, Guigen 📂 Article 📅 2014 🏛 John Wiley and Sons 🌐 English ⚖ 367 KB

## Abstract A concise thiolation of the C(__sp__^3^)H bond of cycloalkanes with diaryl disulfides in the presence of the oxidant di‐__tert__‐butyl peroxide (DTBP) has been developed. This reaction, without using any metal catalyst, tolerates varieties of disulfides and cycloalkanes substrates, giv