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Metal-Free Catalyst for the Chemoselective Methylation of Amines Using Carbon Dioxide as a Carbon Source

✍ Scribed by Das, Shoubhik; Bobbink, Felix D.; Laurenczy, Gabor; Dyson, Paul J.


Book ID
126986361
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
491 KB
Volume
53
Category
Article
ISSN
0044-8249

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Supercritical carbon dioxide as solvent
✍ Donald J. Darensbourg; Nicole White Stafford; Takumi Katsurao πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 313 KB

Supercritical carbon dioxide was found to be a suitable substitute for halogenated organic solvents in its copolymerization with propylene oxide. The system was studied utilizing a heterogenous catalyst, zinc glutarate. The polymers were analyzed for selectivity in polycarbonate linkages by 'H NMR s