𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Metal Dependence of Cyclometalation and Arene CH Activation in the Photolysis of cis-H2M[P(CH2CH2CH2PMe2)3] (MFe, Ru) in Benzene

✍ Scribed by Dipl.-Chem. Martin Antberg; Prof. Dr. Lutz Dahlenburg

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
241 KB
Volume
25
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Reversible CH Bond Activation Reactions
Reversible CH Bond Activation Reactions of the N-Heterocyclic Carbene Ligands in Ru(Ph2PCH2CH2CH2PPh2)(IMes)(CO)H2 and Ru(Ph2AsCH2CH2PPh2)(IMes)(CO)H2 (IMes=1,3-Dimesityl-1,3-dihydro-2H-imidazol-2-ylidene)
✍ Mark J. Chilvers; Rodolphe F. R. Jazzar; Mary F. Mahon; Michael K. Whittlesey 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB 👁 2 views

## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy