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Metal-Controlled Anion-Binding Tendencies of the Thiourea Unit of Thiosemicarbazones

✍ Scribed by Valeria Amendola; Massimo Boiocchi; Luigi Fabbrizzi; Lorenzo Mosca


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
913 KB
Volume
14
Category
Article
ISSN
0947-6539

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## Abstract Treatment of a range of bis(thiourea) ligands with inert organometallic transition‐metal ions gives a number of novel complexes that exhibit unusual ligand binding modes and significantly enhanced anion binding ability. The ruthenium(II) complex [Ru(Ξ·^6^‐__p__‐cymene)(ΞΊ__S__,__S__β€²,__N‐