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Metal Complexing by Tris Buffer

✍ Scribed by ALLEN, D. E.; BAKER, D. J.; GILLARD, R. D.


Book ID
109657102
Publisher
Nature Publishing Group
Year
1967
Tongue
English
Weight
214 KB
Volume
214
Category
Article
ISSN
0028-0836

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Commercially available tris(3,6\_dioxaheptyl)amine (TD&1) is an effective phase transfer catalyst for reactions with sodium-potassium alloy in tetrahydrofuran. Deoxygenation of acetates, dehalogenation, and hydrolysis of tosylates and mesylates proceed in high yield. The use of a deuterated alcohol