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Metal Complexes with Tetrapyrrole Ligands, LXIX. Facile Synthesis and13C-NMR Spectrum of Dichloro(octaethylporphyrinato)zirconium(IV)

✍ Scribed by Buchler, Johann W. ;Eberle, Mike

Publisher: Wiley (John Wiley & Sons)
Year: 1995
Tongue: English
Weight: 256 KB
Volume: 128
Category: Article
ISSN: 0009-2940
DOI: 10.1002/cber.19951281112

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✦ Synopsis

Zirconium(1V) octaethylporphyrin complex / Dichlorozirconium(1V) porphyrin complex / Precursor of organometallic compounds

The synthesis of dichloro(2,3,7,8,12,13,1?,18-octaethylpor-of organometallic compounds. Zr(oep)C12 was characterized phyrinato)zirconium(IV), Zr(oep)CI,, from zirconium tetra-by elemental analyses, lH-and 13C-NMR, UVNis, and mass chloride and octaethylporphyrin, H2(oep), is described. The spectra. Hydrolysis yielded a mixture of monoand binuclear reported synthesis is a new and simple route to this precursor hydroxy zirconium(1V) porphyrins.

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