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Metal complexes with tetrapyrrole ligands. 62. Carbon-13 NMR spectra of dicerium(III) and dipraseodymium(III) tris(octaethylporphyrinate)

✍ Scribed by Buchler, Johann W.; Loeffler, Juergen; Wicholas, Mark


Book ID
126819788
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
404 KB
Volume
31
Category
Article
ISSN
0020-1669

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## Abstract Complete ^1^H and ^13^C NMR assignments and coordination‐induced shift [CIS, Ξ΄~(complex)~ – Ξ΄~(free ligand)~] calculations for carbon σ‐bonded __ortho__‐metalated rhodium(III) and iridium(III) complexes are described. NMR parameters are used as probes of van der Waals interactions and r