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Metal Complexes of π-Conjugated Polymers

✍ Scribed by Takakazu Yamamoto; Hiroki Fukumoto; Take-aki Koizumi


Book ID
106416963
Publisher
Springer
Year
2009
Tongue
English
Weight
675 KB
Volume
19
Category
Article
ISSN
1053-0495

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Organometallic dehalogenative polycondensation of dihaloaromatic compounds produces various p-conjugated polymers. p-Conjugated polymers with nitrogen in the aromatic ring form metal complexes, and regioregular pconjugated polymers such as head-to-tail poly(3-hexylthiophene-2,5-diyl) (HT-P3HexTh), f

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**A new 1,10‐phenanthroline‐containing π‐conjugated polymer,** the color of which can be tuned from blue to red by metal complexation, has been synthesized. The polymer responds sensitively to various metal ions due to its high coordinating ability, and the Figure shows emission from the polymer–met