✦ LIBER ✦
Metal Complexes of a Tetraazacyclotetradecane Bearing Highly Fluorinated Tails: New Catalysts for the Oxidation of Hydrocarbons under Fluorous Biphasic Conditions
✍ Scribed by Gianluca Pozzi; Marco Cavazzini; Silvio Quici; Simonetta Fontana
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 626 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Thecommercially availabIemacrocycIetetraszacycIotetradecane (cyclam)has beenconverted into the fluorocarbonsoluble Iigand 1 by N-functionalizationwith RFCH20CH2CH20TS 3, wherein RF is a (per)ffuorooxyalkylenic chain. Upon complexation with 1, transition metal salts can be selectivelysolubilizedin fluorocarbonsthusprovidingnew catalystsfor the oxidativefunctionalizationof hydrocarbonsunderfluorousbiphasic(FB)conditions. 01997 Elsevier ScienceLtd.