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Metal complexes of 5-(o)hydroxyphenyl-1,3,4-oxadiazole-2-thione

✍ Scribed by R.A. Rai


Book ID
115975943
Publisher
Elsevier Science
Year
1980
Weight
272 KB
Volume
42
Category
Article
ISSN
0022-1902

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In the title compound, C 9 H 8 N 2 O 2 S, the H atom of the thiol group has been transferred to the neighbouring N atom of the oxadiazole ring. Intermolecular N-HÁ Á ÁN hydrogen bonds exist between adjacent molecules.

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The title compound, C~16~H~36~N^+^·C~8~H~5~N~2~O~2~S^−^, crystallizes with two formula units in the asymmetric unit. In both anions, the oxadiazole ring is almost coplanar with the 2-hydroxyphenyl ring. The anion structure is influenced by intramolecular O—H...N hydrogen bonding. The crystal packing

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.045 wR factor = 0.092 Data-to-parameter ratio = 14.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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A view of (I) with the atom-numbering scheme. Displacement ellipsoids for non-H atoms are drawn at the 50% probability level.