Metal complexes as mediator-titrants for electrochemical studies of biological systems
β Scribed by Jay M. Johnson; H.Brian Halsall; William R. Heineman
- Book ID
- 102629683
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 300 KB
- Volume
- 133
- Category
- Article
- ISSN
- 0003-2697
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β¦ Synopsis
Various redox-active metal complexes were evaluated electrochemically for stability, reversibility, and general utility as mediator-titrants in the 0 to + 1 .O V vs standard hydrogen electrode range. Those complexes which were evaluated and appear to be useful in potentiostatic or potentiometric techniques are Ru(bpy)KlO&, Ru(bpy)&m)2, Wb~~h(N0~12, &WpherWW, co(phenW2, and Co(terpykC12.
π SIMILAR VOLUMES
Ah&act-The electrochermcal preparations of Cr(II)EDTA and related Cr(II) polyammocarboxylate complexes m weakly a&c, aqueous medm are described and their reations mth orgamc molecules am Lscussed It IS confirmed that the Cr(II)L complexes are strong reducmg agents capable of some mtezestmg transform