Metal complexes as ligands bi- and tri-nuclear complexes containing similar and dissimilar metal atoms
✍ Scribed by S.J. Gruber; C.M. Harris; E. Sinn
- Book ID
- 107768355
- Publisher
- Elsevier Science
- Year
- 1967
- Weight
- 185 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0020-1650
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## Abstract Four macrocyclic ligands have been synthesized: 1‐oxa‐4,7,10,13‐tetraazacyclopentadecane (1), 1,4‐dioxa‐7,10,13‐triazacyclopentadecane (2), 1,4‐dioxa‐7,11,14‐triazacyclohexadecane (3), 1,4‐dioxa‐7,11,15‐triazacycloheptadecane (4), one of them 3, for the first time. The protonation const
Following earlier work in our laboratory on mononuclear nucleophilic half-sandwich type compounds with Co, Rh and Ir as metal centers, a series of mono-and dinuclear complexes containing bis(cyclopentadienyl)methane as ligand has been prepared. It is shown that the criterion of metal basicity can be