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Metal-chelating 1,3-bis(2′-pyridylimino)isoindolines

✍ Scribed by Walter O. Siegl

Book ID
112126620
Publisher
Journal of Heterocyclic Chemistry
Year
1981
Tongue
English
Weight
451 KB
Volume
18
Category
Article
ISSN
0022-152X

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1,3-Bis(6-methyl-2-pyridylimino)-2,3-dih
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The title compound, C 20 H 17 N 5 , has two molecules in the asymmetric unit with comparable conformations. In each molecule, the isoindoline group and one methylpyridyl ring are coplanar, while the other methylpyridyl rings form angles with respect to these planes of 43.2 (2) and 37.6 (2) .

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Tetra­kis[μ-1,3-bis­(4-methyl-2-pyridylimino)isoindolin­ato]trimercury(II) dinitrate methanol tetra­solvate
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The title compound, [Hg~3~(C~20~H~16~N~5~)~4~](NO~3~)~2~·4CH~3~OH, consists of a trinuclear Hg^II^ dipositive cation, [Hg~3~(4′-Me__L__)~4~]^2+^, two nitrate anions and four occluded methanol molecules. The Hg atoms of the cation lie on a crystallographic twofold axis and are tetrahedrally coordinat