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Metal-Catalyzed Dimethyl Carbonate Synthesis from Carbon Dioxide and Acetals

โœ Scribed by Sakakura, Toshiyasu; Choi, Jun-Chul; Saito, Yuko; Masuda, Takashi; Sako, Takeshi; Oriyama, Takeshi


Book ID
120527532
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
39 KB
Volume
64
Category
Article
ISSN
0022-3263

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Table 1. Iy5Pt-NMR data for some platinum-tin complexes [a]. 1runs-[PtC1(SnC1~)(PEt~)~] [c] 28954 -4780 -864 Irun~-[Pt(SnCl~)~(PEt,)~] [d] 20410 -5152 -618 [el trans-[PtH(SnCla)(PEt,)2J [fl 9 067 -5302 -426 truns-[PtH(SnCb)(PPh2CH2Ph)2] [fl 10955 -5322 -428 I~u~~-[P~(C(CO,E~)==CHCOZE~)(S~C~~)(PP~~)

Synthesis of dimethyl carbonate from car
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The turnover number of the catalytic production of dimethyl carbonate from CO 2 and methanol is restricted by thermodynamics as well as catalyst decomposition. The catalytic efficiency is remarkably improved using an acetal as the starting material in methanol. The catalytic activity and selectivity