Metal-Catalyzed Dimethyl Carbonate Synthesis from Carbon Dioxide and Acetals
โ Scribed by Sakakura, Toshiyasu; Choi, Jun-Chul; Saito, Yuko; Masuda, Takashi; Sako, Takeshi; Oriyama, Takeshi
- Book ID
- 120527532
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 39 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Table 1. Iy5Pt-NMR data for some platinum-tin complexes [a]. 1runs-[PtC1(SnC1~)(PEt~)~] [c] 28954 -4780 -864 Irun~-[Pt(SnCl~)~(PEt,)~] [d] 20410 -5152 -618 [el trans-[PtH(SnCla)(PEt,)2J [fl 9 067 -5302 -426 truns-[PtH(SnCb)(PPh2CH2Ph)2] [fl 10955 -5322 -428 I~u~~-[P~(C(CO,E~)==CHCOZE~)(S~C~~)(PP~~)
The turnover number of the catalytic production of dimethyl carbonate from CO 2 and methanol is restricted by thermodynamics as well as catalyst decomposition. The catalytic efficiency is remarkably improved using an acetal as the starting material in methanol. The catalytic activity and selectivity