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Metal catalysis in organic reactions. 7. The role of nickel complexes in the reaction of triisobutylaluminum with terminal acetylenes

โœ Scribed by Giacomelli, Giampaolo; Caporusso, Anna Maria; Lardicci, Luciano

Book ID
127350964
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
831 KB
Volume
44
Category
Article
ISSN
0022-3263

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Metal catalysis in organic reactions. 17
Metal catalysis in organic reactions. 17. A nickel-promoted route to substituted allenes by reaction of 1-bromo-1,2-dienes with alkyl metals.
โœ Anna Maria Caporusso; Federico Da Settimo; Luciano Lardicci ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Nickel complexes are found to be catalytically active in the cross-coupling reactions of allenic bromides with alkyl metals to give substituted allenes in excellent yields. The catalytic process proceeds generally with inversion of configuration in the allenyl moiety.