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Metal-Assisted Functionalization of Diphosphines

✍ Scribed by Jose M. Vila; Margarita Lopez-Torres; Casimiro Rodriguez; Alberto A. Fernandez; Roberto Mosteiro; Jesus J. Fernandez

Publisher
John Wiley and Sons
Year
2004
Weight
7 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract We report the triphenyltin‐mediated free‐radical cyclization of 4‐ethynyl‐2,6,6‐trimethylocta‐1,7‐dien‐4‐ol (**1**) and 4‐ethynyl‐6,6‐dimethylocta‐1,7‐dien‐4‐ol (**2**), along with some chemical manipulations of the resulting stannylidene derivatives **3** and **7**. The reaction of int