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Metadiscourse: Exploring Interaction in Writing by HYLAND, KEN

โœ Scribed by HERTA RODINA

Book ID
109161379
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
274 KB
Volume
91
Category
Article
ISSN
0026-7902

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Remarkably fast [2+2]cycloreversion in m
Remarkably fast [2+2]cycloreversion in methoxy substituted Cookson's cage ketones assisted by the capto-dative substituent effect and by the through-bond interaction
โœ Yasushi Okamoto; Ken Kanematsu; Teruyo Fujiyoshi; Eiji Osawa ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 242 KB

1,7-Dimethoxy groups in Cookson's pentacyclic cage ketone derivatives (2 and 2) accelerate the thermal [2+2]cycloreversion, possibly by means of the unusual lengthening of Cl-C7 bond and the synergetic capto-dative stabilization of 1,4\_diradical (7, and 8).