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Metabolism of 2-chloro-4-methylphenoxyacetate byAlcaligenes eutrophusJMP 134

✍ Scribed by Dietmar Helmut Pieper; Karin Stadler-Fritzsche; Karl-Heinrich Engesser; Hans-Joachim Knackmuss

Publisher: Springer
Year: 1993
Tongue: English
Weight: 854 KB
Volume: 160
Category: Article
ISSN: 0302-8933
DOI: 10.1007/bf00249121

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The important herbicide, 2-methyl-4-chlorophenoxyacetic acid (MCPA) was synthesized by the chlorination of 2-methylphenoxyacetic acid with tert-butyl hypochlorite in the presence of methyl N,N-dimethylglycinate as a catalyst, giving a high yield and regioselectivity. The reaction was investigated us