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Mesogen-jacketed liquid crystalline polymer with flexible dicyclopentyl terephthalate as side group

✍ Scribed by Hui-lin Tu; Dong Zhang; Xin-hua Wan; Xiao-fang Chen; Yu-xiang Liu; Hai-liang Zhang; Qi-Feng Zhou

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 40 KB
Volume: 20
Category: Article
ISSN: 1022-1336
DOI: 10.1002/(sici)1521-3927(19991001)20:10<549::aid-marc549>3.0.co;2-j

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✦ Synopsis

For the first time the flexible cyclopentyl ring is used to build mesogenic units, and thus a novel mesogen-jacketed liquid crystalline polymer (MJLCP) poly(dicyclopentyl vinylterephthalate) is synthesized. The polymer forms a stable mesophase which changes to an isotropic phase at 267 8C. The formation of a stable mesophase may be attributed to the spatial interaction among flexible side groups which converts them into rigid mesogenic units.

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