(Mesityl)2Ge(fluorenylidene)–Stabilization of a Ge–C Double Bond by Charge Transfer into an Aromatic System

✍ Scribed by Mohamed Lazraq; Dr. Jean Escudié; Dr. Claude Couret; Prof. Dr. Jacques Satgé; Prof. Dr. Martin Dräger; Dr. Ralph Dammel

• Book ID: 101553797
• Publisher: John Wiley and Sons
• Year: 1988
• Tongue: English
• Weight: 311 KB
• Volume: 27
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198808281

✦ Synopsis

Multiple bonds to elements of groups 14 and 15 have been the subject of broad interest in recent years."] This is especially true for investigations['] on silaethenes 1 stabi-

R,C=StRI

R2C=GeR;

1 2 lized by bulky groups; the analogous germaethenes 2, on the other hand, could only be detected until recently by trapping reaction^.'^] Newly obtained pure germaethenes 3