Mercury(II) Complexes with Thiacrowns and Related Macrocyclic Ligands
β Scribed by Gregory J. Grant
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 11 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
Three N,S2 macrocycles (3,10,12) carrying an amino group as a pendant arm have been synthesized and their complexation properties towards Ni2+ and Cu2+ studied. The crystal structures of the Cu2+ complexes with lO-methyl-l,4-dithia-7,lO-diazacyclododecane-7-ethanamine (3) and 1 1-methyl-1,4-dithia-8
The 14-membered tetraazamacrocyclic Ni2+ and Cuz+ complexes of 4 (1,4,8-trimethyl-ll-[(2-methylthio)ethyl]-1,4,8,11 -tetraazacyclotetradecane), 5 (I ,4-dimethyl-8,11 -bis[2-(methylthio)ethyl]-1,4,8,11 -tetraazacyclotetradecane), and 7 (1,4,8,1 1-tetrakis[2-(methylthio)ethyl]-1,4,8,ll-tetraazacyclote