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Mercury Photosensitized Isomerization of 1,5-Cycloöctadiene to Tricyclo [3.3.0.0 2,6 ] Octane

✍ Scribed by Srinivasan, R.


Book ID
120325288
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
274 KB
Volume
85
Category
Article
ISSN
0002-7863

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Tricyclo[6.3.0.01,6]Undecan-2-one and it
✍ R.L. Cargill; J.R. Dalton; S. O'Connor; D.G. Michels 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 108 KB

We report the formation of the tricyclo[6.3.0.01\*6]undecanones x and 2, and the unusual acid-catalyzed isomerization of $, to &$. Irradiation of 1" in hexane gave z3s4 as the sole product isolated in 92% yield. Similar irradiation of ,$" gave only 2 (83%). Wolff-Kishner reduction of the new ketones