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Mercury halide complexes of tertiary phosphines.: Part XVI. Dimer–monomer trend in the 1:1 complexes of mercury(II) halides with bulky tris(2,6-dimethoxyphenyl)phosphine (DMPP)

✍ Scribed by Norman A Bell; Simon J Coles; Michael B Hursthouse; Mark E Light; K.Abdul Malik; Rafizah Mansor

Book ID: 108427941
Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 354 KB
Volume: 19
Category: Article
ISSN: 0277-5387
DOI: 10.1016/s0277-5387(00)00451-4

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Cadmium(II) halide complexes of tertiary

Cadmium(II) halide complexes of tertiary phosphines. Part II. Structural variations in the 1:1 series, CdX2(PR3)

✍ N.A. Bell; T.D. Dee; M. Goldstein; I.W. Nowell 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 180 KB

We have recently shown [ 1 ] how significant vanatlon in the structures of HgX2(PR3) complexes [l-3 ] can be rationalised in terms of the varying u-donor strengths of the PRs ligands coupled with the tendency for mercury(H) towards linear co-ordination. Cadmium shows no such preference for digonal g