Mercuric Triflate Catalyzed Hydroxylative Carbocyclization of 1,6-Enynes.
β Scribed by Mugio Nishizawa; Veejendra K. Yadav; Mariusz Skwarczynski; Hiroko Takao; Hiroshi Imagawa; Takumichi Sugihara
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 168 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Bi(OTf)~3~ effectively catalyzed the cyclization of aminoβ1,6βenynes, leading to bicyclic amine and cyclopentadienyl amino compounds. The selectivity of the products depends on the substitution pattern of the olefinic moiety. ^19^F NMR trace experiment of the reaction and other results