Meniscus and Precursor Film in Steady-State Wetting
β Scribed by Oleg V. Voinov
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 149 KB
- Volume
- 201
- Category
- Article
- ISSN
- 0021-9797
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β¦ Synopsis
The a 1 parameter may readily be expressed via the parameter Consideration is given to the stationary motion of a capillary PΛin (9), a 1 Γ 2/3PΛ. Reference (5) provides a simplified meniscus of a wetting liquid over a solid at rather slow speeds contact angle relation relying upon the perturbation method when a precursor film moved by van der Waals forces exists. A and the assumption that a 1 has a small value. It is of interest transient region between (I) the meniscus motion with a dynamic to evaluate the effectiveness of this solution by comparing contact angle and (II) the slow-wetting regime is studied. The it to numerical analysis data.
dependence of the dynamic contact angle on the wetting velocity
As the asymptotic theory shows, the dynamic contact is derived. The phenomenon of zero contact angle at a nonzero angle a 0 exists when a 1 is small or PΛis great (PΛΣ· 1).
critical speed is demonstrated. The numerically obtained interrela-At low values (PΛΣΆ 1) we have slow wetting in which the tion between the contact angle and the velocity is compared to that provided by the asymptotic theory. The asymptotic equations precursor film starts from the equilibrium transient zone of for the meniscus contact angle is shown to be highly effective over the meniscus. The intermediate regime of wetting dynamics a wide range of nondimensional velocities. The meniscus contact (PΛΓ 1) is analyzed below. In this regime, the dependence angle existence criterion is refined. Dependence of the initial thickof the contact angle on the wetting rate must substantially ness of the precursor film on the speed is estimated. The conditions differ from that previously known (a 0 Γ Ca 1/3 ).
of the initial thickness, being in correspondence with the slow-
We would employ the previously known parabolic apwetting regime, are outlined.
π SIMILAR VOLUMES
## Ahatract -The steady state behavior of two simple passivation models are examined by varying the functional forms of adsorption, desorption and homogeneous reaction rates in one case and surface reaction rates in the other case. Multiple steady states and oscillations can occur when a factor of
The authors' new one-dimensional free coating theory is considered further, and compared with previous theories. It is shown that a unique value of the dimensionless film thickness, TO, exists over a wide range of Capillary Number, Ca. The shape of the upper meniscus is predicted from the new one-di