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Memory effects in polyaniline in mixed solvents

โœ Scribed by Heqing Tang; Akira Kitani; Masaru Shiotani


Publisher
Elsevier
Year
1995
Tongue
English
Weight
580 KB
Volume
396
Category
Article
ISSN
1572-6657

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Solvent diffusion in a modified polyanil
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A dodedyl benzene sulfonic acid doped polyaniline was synthesized and cast into films. Water and ethanol were used as the main diffusional probes to study this polymer from 25ะŠC to 45ะŠC. Sorption of water in this polymer was found to be almost independent of temperature, but sorption of ethanol in t

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Modeling results indicate that polymer chains in mixtures of a good with a bad solvent exhibit preferential adsorption of the good solvent. That phenomenon is found to be strongly dependent on molecular weight and it increases with a decrease in chain length. These results have important consequence