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Melting behavior of cis-polybutadiene crystallized under stress

✍ Scribed by F. De Candia; G. Romano

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
409 KB
Volume
38
Category
Article
ISSN
0021-8995

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✍ Fabio Bertini; Maurizio Canetti; Giovanni Ricci πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 124 KB

## Abstract 1,2‐Syndiotactic polybutadiene was synthesized at βˆ’30Β°C using the catalyst system CrCl~2~(dmpe)~2~‐MAO. The syndiotactic index of the butadiene sequences, expressed as a percentage of syndiotactic pentads [rrrr], was evaluated by ^13^C‐NMR measurements. WAXD and SAXS techniques were emp