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Melting and crystallization behavior of polyhedral oligomeric silsesquioxane-capped poly(ε-caprolactone)

✍ Scribed by Yong Ni; Sixun Zheng


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
241 KB
Volume
45
Category
Article
ISSN
0887-6266

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## Abstract Novel fullerene‐ and polyhedral oligomeric silsesquioxane‐ (POSS) double end‐capped poly(__ε__‐caprolactone) (PCL) were successfully synthesized. The crystallization behavior of the fullerene‐ and POSS‐ double end‐capped PCL and the effect of aggregation of the POSS and fullerene moieti

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The nonisothermal crystallization behavior and melting process of the poly(1-caprolactone) (PCL)/poly(ethylene oxide) (PEO) diblock copolymer in which the weight fraction of the PCL block is 0.80 has been studied by using differential scanning calorimetry (DSC). Only the PCL block is crystallizable,