## Abstract Novel fullerene‐ and polyhedral oligomeric silsesquioxane‐ (POSS) double end‐capped poly(__ε__‐caprolactone) (PCL) were successfully synthesized. The crystallization behavior of the fullerene‐ and POSS‐ double end‐capped PCL and the effect of aggregation of the POSS and fullerene moieti
Melting and crystallization behavior of polyhedral oligomeric silsesquioxane-capped poly(ε-caprolactone)
✍ Scribed by Yong Ni; Sixun Zheng
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 241 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0887-6266
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130025, People's Republic of China ## SYNOPSIS The isothermal crystallization and melting behavior of the poly(c-caprolactone)(PCL)/ poly(ethy1ene oxide)( PEO) diblock copolymer has been studied by WAXD, SAXS, and DSC methods. Only the PCL block is crystallizable; the PEO block of weight fraction
The nonisothermal crystallization behavior and melting process of the poly(1-caprolactone) (PCL)/poly(ethylene oxide) (PEO) diblock copolymer in which the weight fraction of the PCL block is 0.80 has been studied by using differential scanning calorimetry (DSC). Only the PCL block is crystallizable,