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Melt spinning of polymers I. An elementary framework for analyzing the development of orientation

✍ Scribed by A. S. Abhiraman; G. E. Hagler


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
844 KB
Volume
33
Category
Article
ISSN
0021-8995

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✦ Synopsis


An elementary framework to describe the evolution of orientational order in melt spinning of polymers is presented. By dividing this process into fundamentally different zones of structure development (melt zone with T > temperature of initiation of crystallization T,; crystallization zone with T, > T > 2''; static zone with T < Tg), it is shown that a generalized framework can be developed into which different homopolymers can be fitted on the basis of their physical transition temperatures. Sources of deviation from the simplified framework are also discussed.