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Melt blends of polyethylene with a phenoxy

โœ Scribed by Chi Hoon Choi; Byung Kyu Kim


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
319 KB
Volume
31
Category
Article
ISSN
0014-3057

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โœฆ Synopsis


Melt blends of high density polyethylene (PE) with a phenoxy have been prepared over a full composition range using a Brabender Plasticorder. Scanning electron microscopy @EM) micrographs showed a clear phase separation, viz. particle-in-matrix or co-continuous morphology depending on the composition. T,,, (crystalline melting temperature) of PE decreased by 3-6"C, whereas TF (glass transition temperature) of phenoxy increased up to ca 11ยฐC in the blends. Mechanical propertIes of the blends showed a negative deviation from linear additivity due to large phase separation (-several pm) and poor interfacial adhesion.


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