Medium effects on the reactions of coordination complexes: Base hydrolysisof(αβS)(p-hydroxybenzoato)(tetraethylenepentamine) cobalt(III) in iso-propanol–water, tert-butanol–water and dimethyl sulfoxide–water media

Effects of solvent on the reactions of c

Effects of solvent on the reactions of coordination complexes: Part 17. Kinetics and mechanism of base hydrolysis of (αβS) (salicylato) (tetraethylenepentamine)cobalt (III) in methanol + water and dimethylsulphoxide + water media

✍ Anadi C. Dash; Prafulla K. Das 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 611 KB

The base hydrolysis of (apS) (salicylato) (tetraethylenepentamine)cobalt(III) has been investigated in MeOH + water and DMSO + water media (0-70% (viv) cosolvents) at 20.0 I t"C I 35.0 and I = 0.10 mol dm-3 (clod-). The phenoxide species [(tetren)Co02CC,H40]' undergoes both OH--independent and OH--c