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Medium effects on the lifetime and reactivity of triplet exciplexes

โœ Scribed by Roy, J. K.; Whitten, David G.


Book ID
126888967
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
389 KB
Volume
94
Category
Article
ISSN
0002-7863

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Absorption spectrum, lifetime and reacti
โœ J.C. Scaiano; D. Weir ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 456 KB

The first excited triplet state of dimesitylcarbene has been generated in solution at room temperature. It has a lifetime of 60 ns and shows fluorescence with A mp~ = 501 nm and absorption with A,,. = 360 nm. This species is quenched by oxygen and carbon tetrachloride with rate constants of (4.4kO.8