Medium effects for single ions in acetonitrile and ethanol-water solvents based on reference-electrolyte assumption

Effects of urea, Na+ and Li+ ions on the

Effects of urea, Na+ and Li+ ions on the kinetics and mechanism of intramolecular general base-catalyzed glycolysm of ionized phenyl salicylate in ethane-1,2-diol–acetonitrile solvents at a constant water concentration

✍ M. Niyaz Khan 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 120 KB 👁 2 views

Pseudo-first-order rate constants (k 1 ) for the reaction of ethane-1,2-diol (DOL) with ionized phenyl salicylate (PS À ), obtained in mixed DOL-CH 3 CN solvent at constant [H 2 O] and [NaOH], obey the relationship , where a is the apparent second-order rate constant, K A is the association constan