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Mechanochemical synthesis and characterization of poly(vinyl chloride)-block-poly(vinyl alcohol) copolymers by ultrasonic irradiation

✍ Scribed by Hideki Fujiwara; Takaaki Ishida; Naomi Taniguchi; Seiji Wada


Publisher
Springer
Year
1999
Tongue
English
Weight
173 KB
Volume
42
Category
Article
ISSN
0170-0839

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ABA-type block copolymers containing segments of poly(dimethyl siloxane) and poly(vinyl pyrrolidinone) were synthesized. Dihydroxyl-terminated poly(dimethyl siloxane) was reacted with isophorone diisocyanate and then with t-butyl hydroperoxide to obtain macroinitiators having siloxane units. The per