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Mechanistic study on the opposite migration order of clenbuterol enantiomers in capillary electrophoresis with β-cyclodextrin and single-isomer heptakis(2,3-diacetyl-6-sulfo)-β-cyclodextrin

✍ Scribed by Bezhan Chankvetadze; Ketevan Lomsadze; Dieter Bergenthal; Jörg Breitkreutz; Klaus Bergander; Gottfried Blaschke

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 124 KB
Volume: 22
Category: Article
ISSN: 0173-0835
DOI: 10.1002/1522-2683(200109)22:15<3178::aid-elps3178>3.0.co;2-f

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The single isomer, fully and permanently charged heptakis-2,3-di-. methyl-6-sulfato -␤-cyclodextrin was used to study the complexation behavior of the enantiomers of noncharged analytes in capillary electrophoresis. Separation selectivities were calculated from the measured effective mobilities and