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Mechanistic study of the termination reactions of 2,4,6-trialkylphenoxy radicals carboxylic acids

✍ Scribed by Weiner, S. A.; Mahoney, L. R.

Book ID
121384144
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
479 KB
Volume
94
Category
Article
ISSN
0002-7863

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Mechanistic study of the gas-phase react
Mechanistic study of the gas-phase reaction of CH2FO2 radicals with HO2
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Fourier transform infrared spectroscopy was used to identify CH2FOOH and HC(O)F as products of the gas-phase reaction of CHIFOz radicals with HOs radicals. At 700 Torr and 295 + 2 K, branching ratios for the CHrFOOH forming channel, k,,/k, =0.29 f 0.08 and the HC(O)F channel, klb/kl =0.71 f 0.11 wer