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Mechanistic Studies on the Cyclization of ( Z )-1,2,4-Heptatrien-6-yne in Methanol: A Possible Nonadiabatic Thermal Reaction

✍ Scribed by Cremeens, Matthew E.; Hughes, Thomas S.; Carpenter, Barry K.

Book ID
125835243
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
170 KB
Volume
127
Category
Article
ISSN
0002-7863

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✍ Hofmann, JΓΆrg ;Zimmermann, Gerhard ;Homann, Klaus-Heinrich πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 784 KB

The gas-phase pyrolysis of 1,4-diphenyl-l-buten-3-yne (1) was investigated in the temperature range between 600 and 800Β°C and in the presence of different carrier gases (N2, N2/ toluene, H2). By a detailed analysis (GC, GC/MS, GC/FTIR) all volatile reaction products were identified and quantitativel